Stoichiometric reduction of coordination polymers by organometallic complexes
نویسندگان
چکیده
منابع مشابه
On the π coordination of organometallic fullerene complexes.
Novel organometallic complexes of fullerene C₈₀ and aryl ligands were simulated. The nature and characteristics of this family of complexes involving π coordination between the fullerene and a metal centre have been studied from a theoretical point of view. We are particularly interested in complexes where η⁶ coordination is present, this being the strangest manifestation of known coordinations...
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The different coordination modes in fullerene organometallic complexes are reviewed. The main modes are η2 and η5, but there are some interesting studies about the other four, all of them are revised in order to show which is the state of art of this kind of compounds with the respect of the hapticity.
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Organometallic complexes offer chemistry that is not accessible to purely organic molecules and, hence, potentially new mechanisms of drug action. We show here that the presence of both an iodido ligand and a sigma-donor/pi-acceptor phenylazopyridine ligand confers remarkable inertness toward ligand substitution on the half-sandwich "piano-stool" ruthenium arene complexes [(eta(6)-arene)Ru(azpy...
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The synthesis of hexanuclear lanthanide hydroxo complexes by controlled hydrolysis led to polymorphic compounds. The hexanuclear entities crystallize in four different ways that depend on the extent of their hydration. The four structures can be described as hexanuclear lanthanide entities with formula [Ln(6)(mu(6)-O)(mu(3)-OH)(8)(NO(3))(6)(H(2)O)(12)](2+). Two additional NO(3)(-) ions intercal...
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The chemistry of metal cyclopropenyl complexes derived from deprotonation of cationic ruthenium vinylidene complexes is reviewed. Such a metal coordinated cyclopropenyl ligand can be used for the preparation of heterocyclic compounds. The chemical reactivity of cyclopropenyl complexes is influenced by the nature of substituents on the three-membered ring and by the nature of ancillary ligand ar...
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ژورنال
عنوان ژورنال: Acta Crystallographica Section A Foundations of Crystallography
سال: 2010
ISSN: 0108-7673
DOI: 10.1107/s0108767310094651